I am not sure on when I turned 110, but i have been watching the active world pet quests, they seem to go active approx 10-11 AM CSThttp://www.wowhead.com/world-quests/na
currently i am 2 trainers away from Family Familiar using the same technique described above, one character that is 110 without world quests, and the other toon with WQ to track them.
Turns out that Suramar has 2 Trainers that are locked, Aulier and Varenne. Unfortunately,to use those trainers, you have to have that location in suramar unlocked. Varenne is vineyards I think, and Aulier is Menagerie I think. At the time it showed up on wowhead, I had not unlocked those areas.
Snail Fight - with Odrogg I have never seen yet.
Training with Durian: I have never seen yet.
I wont count Flummox as his family familiar achievement appears bugged.
it has been real frustrating seeing all the other WQ pop and repop multiple times, but still have not seen those trainers nor these other pet battle WQ.
Size Doesnt Matter (Azuna)
Clear the Catacombs (Suramar)
Mana Tap (Suramar)
Only pets can prevent forest fires (Val Sharah)
Snail Fight (High Mountain)
The Master of Pets (Suramar)
Chopped (Suramar) - was popped in last weekish did not have area unlocked.
Threads of Fate (Suramar)
Training with Durian (Val Sharah)