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Blue-quality Skimmers do exist!
Caught mine this afternoon. 5:30 pm ET on Bronzebeard (a Pacific server). It was the second pet to a White-quality Golden Civet, with a Grey-quality Civet finishing out the triad. I'd seen a few other Grey-quality Skimmers paired with Civets or Bullfrogs, so check all those you can find when hunting your Blue.
Location: Vale of Eternal Blossoms \ The Emperor's Approach
Best of luck to everyone still searching!
As stated in a post about Battle Teams, I have many different groupings based on a specific theme. Each of the pets on my teams are named; this is just one reason why someone might want multiples of a given pet. And if we're going to use our teams in pet battles (as I do), the rare pet is better than a gray. So, there are legitimate reasons for capturing more than one rare of a species.
Courtesy is covered by announcing my hunt in General Chat.