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Have tried looking for this at night, during the day, and just now.. finally, found a lone poor quality up in the plateau behind the Portal in Blasted Lands.
Realm time was around 9:30am on the Blade's Edge server.
These are EXTREMELY rare to find at all it seemed when I went after them today. Slaughtered everything I could to see if it helped with spawning, but nothing happened right away.
Maybe it was because I had just finished off Broodmother Slivina, the golden elite in the area, but it wasn't long afterwards that I found a RARE.
Time was around 5:20pm realm time.
*edit* Noticed that there were no other spawns after my battle.
Good luck in your hunting!
Found three of these hanging around the Dalaran Crater.. and there were plenty of rats.
Amazingly, I was also able to capture my Rare as my first battle!
Next two were both poor though.